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产品别名
1452829-00-3
SnAP TM试剂
SnAP TM Reagent
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C15H35NSSn |
| Molecular weight | 380.22 |
| MDL number | MFCD23703162 |
| PubChem Substance ID【PubChem化学物质编号】 | 329768678 |
| NACRES | NA.22 |
| General description【一般描述】 | SnAP (Sn amino protocol) reagents have been developed by the Bode group. SnAP reagents are air and moisture stable. They can be prepared from simple reactions with cheap raw materials. SnAP 2-Spiro-(4-Pip) M, also referred to as SnAP 2-spiro-(4-piperdine) morpholine, is a regioisomeric SnAP reagent. This reagent can be prepared from N-Boc piperidone. |
| Application【应用】 | SnAP Reagents provide a one-step route, in tandem with various aldehyde substrates, to saturated N-heterocycles. The synthesis of N-heterocycles through SnAP Reagents requires mild reaction conditions, and aldehydes bearing aryl, heteroaryl, glyoxyl, aliphatic, and halogenated groups are well tolerated. This product was introduced in collaboration with the Bode Research Group SnAP TM Reagent may be used to synthesize 3-substituted thiomorpholines from aldehydes. It may also be used in the preparation of unprotected, saturated N-heterocyclic compounds. |
| Other Notes【其他说明】 | Technology spotlight: SnAP Reagents Professor product portal: Jeffrey Bode Research Group SnAP Reagents for the Synthesis of Piperazines and Morpholines SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes SnAP Reagents for a Cross-Coupling Approach to the One-Step Synthesis of Saturated N-Heterocycles Bespoke SnAP Reagents for the Synthesis of C-Substituted Spirocyclic and Bicyclic Saturated N-Heterocycles |
产品性质
| form【形式】 | liquid |
| Quality Level【质量水平】 | 100 |
| refractive index【折射率】 | n |
| density | 1.158 at 25 ℃ |
| storage temp.【储存温度】 | −20℃ |
| SMILES string | CCCC[Sn](CCCC)(CSCCN)CCCC |
| InChI | 1S/3C4H9.C3H8NS.Sn/c3*1-3-4-2;1-5-3-2-4;/h3*1,3-4H2,2H3;1-4H2; |
| InChI key | DYBMHPJDHUKXRF-UHFFFAOYSA-N |
| packaging【包装】 | 1 g in glass bottle |
安全信息
| Pictograms【象形图】 | GHS06,GHS09 |
| Signal word【警示用语：】 | Danger |
| Hazard Statements | H301 + H311 + H331 - H315 - H319 - H335 - H410 |
| Precautionary Statements | P273 - P280 - P301 + P310 + P330 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338 |
| Hazard Classifications【危险分类】 | Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| Target Organs【靶器官】 | Respiratory system |
| Storage Class Code【储存分类代码】 | 6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects |
| WGK | WGK 3 |
