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4-[(三甲基硅基)乙炔基]苯甲醛

4-[(Trimethylsilyl)ethynyl]benzaldehyde
产品编号:3303632
规格:97%
CAS NO:77123-57-0
包装规格:5 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
33036325 G1420
产品别名

77123-57-0

4-[(三甲基硅基)乙炔基]苯甲醛

4-[(Trimethylsilyl)ethynyl]benzaldehyde

结构式
基本信息
Linear Formula【线性分子式】
(CH3)3SiC≡CC6H4CHO
Molecular weight
202.32
MDL number
MFCD02093765
PubChem Substance ID【PubChem化学物质编号】
24874332
NACRES
NA.22
General description【一般描述】
4-[(Trimethylsilyl)ethynyl]benzaldehyde can be synthesized by reacting 4-bromobenzaldehyde and triphenylphosphine in anhydrous triethylamine with ethynyltrimethylsilane and then with palladium(II) acetate under argon. It can also be prepared by Sonogashira coupling reaction between 4-bromobenzaldehyde and (trimethylsilyl) ethynyl.
Application【应用】
4-[(Trimethylsilyl)ethynyl]benzaldehyde may be used in the preparation of the following:
  • 4,4,5,5-tetramethyl-2-{4-[(trimethylsilyl)ethynyl]phenyl}imidazolidine-1,3-diol
  • 5,10,15-triphenyl-20-{4-[2-(trimethylsilyl)ethynyl]phenyl}porphyrin
产品性质
Quality Level【质量水平】
200
Assay【测定】
97%
mp
66-70 ℃ (lit.)
SMILES string
C[Si](C)(C)C#Cc1ccc(C=O)cc1
InChI
1S/C12H14OSi/c1-14(2,3)9-8-11-4-6-12(10-13)7-5-11/h4-7,10H,1-3H3
InChI key
UZQDUXAJFTWMDT-UHFFFAOYSA-N
packaging【包装】
5 g in glass bottle
安全信息
Storage Class Code【储存分类代码】
13 - Non Combustible Solids
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
Eyeshields, Gloves, type N95 (US)
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