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N-环己基马来酰亚胺

N-Cyclohexylmaleimide
产品编号:3169947
规格:97%
CAS NO:1631-25-0
包装规格:5 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
31699475 G1650
产品别名

1631-25-0

N-环己基马来酰亚胺

N-Cyclohexylmaleimide

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C10H13NO2
Molecular weight
179.22
EC number【EC 号】
216-630-6
MDL number
MFCD00043904
PubChem Substance ID【PubChem化学物质编号】
24863825
NACRES
NA.22
General description【一般描述】
N-Cyclohexylmaleimide (CHMI, NCMI) is a cyclic imide. Diels-Alder reactions of 9-hydroxymethylanthracene with CHMI catalyzed by hydrophobic nanospace confined within the self-assembled Pd6 open cage bearing triimidazole walls have been reported. It undergoes Diels-Alder reactions with various aromatic hydrocarbons promoted by self-assembled coordination cage. This cage acts as nanometer-sized molecular flask and hence promotes this reaction. CHMI is reported to undergo radical polymerization readily under various polymerization conditions to afford poly(CHMI), having excellent thermal stability.
Application【应用】
N-Cyclohexylmaleimide (CHMI, NCMI) may be used for the preparation of hyperbranched copolymers of p-(chloromethyl)styrene (CMS) and NCMI, via atom transfer radical copolymerization reaction.
N-Cyclohexylmaleimide contaminated with N-cyclohexylmaleamic acid (less than 0.9 wt%) may be used for the heat-resistant poly(methyl methacrylate) resin free from coloration and for methyl methacrylate homopolymer. It may be used as monomer in the preparation of styrene/N-cyclohexylmaleimide copolymers with small polydispersities and controlled molecular weights, via free radical copolymerization. It may be used in the synthesis of hyperbranched copolymers by the atom transfer radical copolymerization with p-(chloromethyl)styrene catalyzed by CuCl/2,2′-bipyridine in cyclohexanone or anisole.
产品性质
Quality Level【质量水平】
100
Assay【测定】
97%
mp
89-91 ℃ (lit.)
SMILES string
O=C1C=CC(=O)N1C2CCCCC2
InChI
1S/C10H13NO2/c12-9-6-7-10(13)11(9)8-4-2-1-3-5-8/h6-8H,1-5H2
InChI key
BQTPKSBXMONSJI-UHFFFAOYSA-N
packaging【包装】
5 g in glass bottle
安全信息
Pictograms【象形图】
GHS06,GHS09
Signal word【警示用语:】
Danger
Hazard Statements
H301 - H315 - H317 - H319 - H335 - H410
Precautionary Statements
P261 - P273 - P280 - P301 + P310 - P302 + P352 - P305 + P351 + P338
Hazard Classifications【危险分类】
Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1A - STOT SE 3
Target Organs【靶器官】
Respiratory system
Storage Class Code【储存分类代码】
6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
dust mask type N95 (US), Eyeshields, Gloves
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